75593-76-9Relevant articles and documents
Versatile synthesis of PR2NR′ 2 ligands for molecular electrocatalysts with pendant bases in the second coordination sphere
Doud, Michael D.,Grice, Kyle A.,Lilio, Alyssia M.,Seu, Candace S.,Kubiak, Clifford P.
, p. 779 - 782 (2012)
Two 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligands with alkyl-substituted phosphines have been synthesized via a versatile method that allows for improved control of the phosphine substituent. The methyl- and benzyl-substituted phosphine P2N2 ligands (P Me2NPh2 and PBn 2NPh2) were synthesized and characterized by 31P{1H} NMR, 1H NMR, and elemental analysis, and their corresponding [Ni(PR2NPh 2)2](BF4)2 complexes were synthesized and characterized by 31P{1H} NMR, 1H NMR, and electrochemistry. The structure of the complex [Ni(P Me2NPh2)2](CF 3SO3)2 was characterized by X-ray crystallography.