75609-01-7Relevant academic research and scientific papers
1,3,4-OXADIAZINE DERIVATIVES FROM CYCLOHEXANONE ENAMINES AND ASYMMETRIC DIIMIDES; POSSIBILITY OF RING-CHAIN TAUTOMERISM IN SUCH HETEROCYCLIC SYSTEM
Forchiassin, M.,Risaliti, A.,Russo, C.
, p. 2921 - 2928 (1981)
1,3,4-oxadiazine derivatives, in equilibrium with their corresponding trisubstituted enamine isomers, are obtained in a regiospecific way from cyclohexanone enamines and ethoxycarbonyl aroyl diimides.Such an equilibrium is not present in analogous oxadiazine systems, derived from aryl aroyl diimides.
1,2-Diphenyl-3,5-dimethyl-4-oxo-6,7-diazabicyclohept-2-ene, a nitrogen unsubstituted diazetidine with an unusually unreactive nitrogen.
McIntyre, Deane D.,MacKay, Donald,Wong, Lichin L.
, p. 1316 - 1323 (2007/10/02)
In the title ring system, the benzylic nitrogen (N7), whether substituted or not, is abnormally unreactive.Hydrolysis of the di-urethanes 3a or b occurs readily at N6 to give 10a or b, but not at all at N7.In 3d Pd-H2 remo
