75645-31-7Relevant academic research and scientific papers
Novel immobilized hydrosilylation catalysts based on rhodium 1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidenes
Imlinger, Nicolas,Wurst, Klaus,Buchmeiser, Michael R.
, p. 47 - 57 (2007/10/03)
The reactivity of a well defined Rh (I) complex, i.e. Rh(CF 3COO)(NHC)(COD) (1, NHC = 1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6- tetrahydropyrimidin-2-ylidene, COD = η4-cycloocta-1,5-diene) in the hydrosilylation of 1-alkenes, alkynes,
Rh(1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene) (COD) tetrafluoroborate, an unsymmetrical Rh-homoazallylcarbene: Synthesis, X-ray structure and reactivity in carbonyl arylation and hydrosilylation reactions
Imlinger, Nicolas,Wurst, Klaus,Buchmeiser, Michael R.
, p. 4433 - 4440 (2007/10/03)
The synthesis of novel Rh(1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6- tetrahydropyrimidin-2-ylidene)(COD) tetrafluoroborate (1, COD = η4-1,5-cyclooctadiene) is described. The N-heterocyclic carbene acts as a bidentate ligand with the carbene coordinating to the Rh(I) center and an arene group acting as a homoazallyl ligand. 1 was used in various carbonyl arylation and hydrosilylation reactions allowing the formation of the desired products with unprecedented selectivity and efficiency. Thus, turn-over numbers (TONs) up to 2000 were achieved.
HETEROMETALLIC CARBIDOCARBONYL CLUSTERS AS CATALYSTS FOR THE HYDROSILYLATION OF ACETYLENE COMPOUNDS
Kopylova, L. I.,Pukhnarevich, V. B.,Gurevskaya, L. B.,Tsybenov, M. Ts.,Voronkov, M. G.
, p. 279 - 283 (2007/10/02)
New active heterometallic hydridocarbonyl iron-rhodium complexes are proposed as catalysts for the hydrosilylation of phenylacetylene with trichloro-, alkyldichloro-, and dialkylchloro-silanes.The activity of these clusters is determined mainly by the pre
