756524-49-9Relevant academic research and scientific papers
First planar chiral bidentate ligand based on a (η5- cyclopentadienyl)(η4-cyclobutadiene) cobalt backbone: High efficiency in enantioselective palladium-catalyzed allylic substitutions
Gomez Arrayas, Ramon,Garcia Mancheno, Olga,Carretero, Juan C.
, p. 1654 - 1655 (2008/10/09)
The synthesis of the planar chiral (R)-[η5-(1- diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4- tetraphenylcyclobutadiene) cobalt and its high efficiency as P,S-bidentate ligand in Pd-catalyzed allylic substitutions is described.
