75662-87-2

Basic information

• Product Name: [1,2-bis(diphenylphosphino)ethane]chloro(phenylazoacetaldoximato)palladium(II)
• Synonyms: [1,2-bis(diphenylphosphino)ethane]chloro(phenylazoacetaldoximato)palladium(II)
• CAS NO: 75662-87-2
• Molecular Weight: 702.468
• Mol File: 75662-87-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1,2-bis(diphenylphosphino)ethane]chloro(phenylazoacetaldoximato)palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: [1,2-bis(diphenylphosphino)ethane]chloro(phenylazoacetaldoximato)palladium(II)(75662-87-2)
• EPA Substance Registry System: [1,2-bis(diphenylphosphino)ethane]chloro(phenylazoacetaldoximato)palladium(II)(75662-87-2)

Safety Data

• Hazardous Substances Data: 75662-87-2(Hazardous Substances Data)

Upstream product

• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Downstream Products

• 19978-61-1 (1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II) 
• 63056-54-2 bis(phenylazoacetaldoximato)palladium(II) 

Relevant articles and documents

Selective Cleavage of the Two Types of Pd-N Bonds in Di-μ-halogeno-bis

Triarylphosphines split the halogen bridge of the title complex and also open the arylazo-oximato chelate ring at the azo-end.In solution an equilibrium exists between the closed-ring and open-ring species.The equilibrium constants are reported.Bidentate phosphine and phosphinoarsine simultaneously split the bridge and cleave the Pd-N(azo) bond.Anhydrous HCl gas protonates the oximato-group with its concomitant displacement by Cl-ion; in effect the Pd-N(oxime) bond is selectively cleaved.