75677-05-3

Basic information

• Product Name: Benzenepentanal, 4-(phenylmethoxy)-
• CAS NO: 75677-05-3
• Molecular Formula: C18H20O2
• Molecular Weight: 268.356
• Mol File: 75677-05-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenepentanal, 4-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepentanal, 4-(phenylmethoxy)-(75677-05-3)
• EPA Substance Registry System: Benzenepentanal, 4-(phenylmethoxy)-(75677-05-3)

Safety Data

• Hazardous Substances Data: 75677-05-3(Hazardous Substances Data)

Upstream product

• 18742-02-4 2-bromo-2-(2-ethyl)dioxolane 
• 883020-47-1 2-[2-(4-benzyloxyphenyl)-ethyl]-1,3-dioxolane 
• 108-20-3 di-isopropyl ether 
• 23915-08-4 2-benzyloxybenzyl chloride 

Downstream Products

• 75677-20-2 ethyl 9-(p-benzyloxyphenyl)-3-hydroxy-3-methyl-trans-4-nonenoate 
• 75677-36-0 5H-r,9-(p-benzyloxyphenyl)-cis-4-bromo-cis-3-hydroxy-trans-3-methylnonan-5-olide 
• 75677-56-4 5H-r,9-(p-benzyloxyphenyl)-cis-3-hydroxy-trans-3-methylnonan-5-olide 

Relevant articles and documents

Rhodium-Catalyzed Remote C(sp3)?H Borylation of Silyl Enol Ethers

A rhodium-catalyzed remote C(sp3)?H borylation of silyl enol ethers (SEEs, E/Z mixtures) by alkene isomerization and hydroboration is reported. The reaction exhibits mild reaction conditions and excellent functional-group tolerance. This method is compatible with an array of SEEs, including linear and branched SEEs derived from aldehydes and ketones, and provides direct access to a broad range of structurally diverse 1,n-borylethers in excellent regioselectivities and good yields. These compounds are precursors to various valuable chemicals, such as 1,n-diols and aminoalcohols.