756834-77-2Relevant articles and documents
Total synthesis of pseudotrienic acid B: A bioactive metabolite from Pseudomonas sp. MF 381-IODS
Amans, Dominique,Bellosta, Veronique,Cossy, Janine
, p. 5870 - 5874 (2006)
(Chemical Equation Presented) Acid advancement: An efficient and highly convergent stereoselective synthesis of pseudotrienic acid B (see structure) has been achieved. Synthetic highlights include a crotyltitanation reaction to control the stereogenic centers at C11 and C20, a cross-metathesis reaction to synthesize the triene moiety, and a Stille cross-coupling reaction to complete the assembly of the carbon framework of the natural product.