75685-17-5

Upstream product

• 75685-16-4 (Z)-(R)-8-((3aR,5R,6aR)-2,2-Dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-8-hydroxy-oct-5-enoic acid methyl ester 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 4005-46-3 (1R)-1-[(3aR,5R,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol 
• 2946-01-2 (3aR,5R,6S,6aR)-5-((R)-1,2-dihydroxyethyl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-yl 4-methylbenzenesulfonate 
• 3253-75-6 1,2:5,6-di-O-isopropylidene-3-O-tosyl-α-D-glucofuranoside 
• 75685-15-3 (R)-8-((3aR,5R,6aR)-2,2-Dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-8-hydroxy-oct-5-ynoic acid methyl ester 
• 75646-89-8 (R)-8-((3aR,5R,6aR)-2,2-Dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-8-hydroxy-oct-5-ynoic acid 
• 2457-93-4 (3aR,5R,6aR)-2,2-dimethyl-5-((S)-oxiran-2-yl)tetrahydrofuro[3,2-d][1,3]dioxole 
• 75646-85-4 3-p-toluenesulphonate of 1,2-O-isopropylidene-5,6-O-methoxymethylidene-α-D-glucofuranose 
• 75646-86-5 1,2-O-isopropylidene-5,6-O-methoxymethylidene-3-deoxy-D-erythro-3,4-hexofuranoside 
• 76119-18-1 1,2-O-isopropylidene-5,6-O-methoxymethylidene-3-deoxy-α-D-xylohexofuranose 
• 53293-00-8 hex-5-ynoic acid 

Downstream Products

• 74595-17-8 (Z)-(8R,9R,11R)-8-(tert-Butyl-diphenyl-silanyloxy)-12,12-bis-ethylsulfanyl-9,11-dihydroxy-dodec-5-enoic acid methyl ester 
• 74581-59-2 methyl 8R-tert-butyldiphenylsilyloxy-9R,11R-dihydroxy-9,11-O-isopropylidene-12-oxo-dodeca-5Z-enoate 
• 74581-59-2 methyl 8R-tert-butyldiphenylsilyloxy-9R,11S-dihydroxy-9,11-O-isopropylidene-12-oxo-dodeca-5Z-enoate 
• 75685-18-6 methyl 8R-tert-butyldiphenylsilyloxy-9R,11R-dihydroxy-9,11-O-isopropylidene-12,12-di(ethylthio)dodeca-5Z-enoate 
• 75646-92-3 methyl 8R-tert-butyldiphenylsilyloxy-9R,11R-dihydroxy-9,11-O-isopropylidene-14-oxo-tetradeca-5Z,12E-dienoate 
• 75646-93-4 methyl 8R-tert-butyldimethylsilyloxy-9R,11R-dihydroxy-9,11-O-isopropylidene-eicosa-5Z,12E,14-trienoate 

Relevant academic research and scientific papers

Oxidation products of arachidonic acid. III. The synthesis of methyl 8R,9R,11R-, 8S,9R,11R-, and 8S,9S,11R-triacetoxyeicosa-5Z,12E,14Z-trienoate

A stereospecific synthesis of the title compounds, starting from readily available glucose derivatives, is described, and methods for differentiating them and the already reported 8R,9S,11R-eicosatrienoate are discussed.