756895-88-2

Basic information

• Product Name: (3aS,6aS)-3-tert-Butyl-5-((S)-1-phenyl-ethyl)-3a,5,6,6a-tetrahydro-1-oxa-4-thia-2,5-diaza-pentalene 4,4-dioxide
• CAS NO: 756895-88-2
• Molecular Weight: 322.428
• Mol File: 756895-88-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3aS,6aS)-3-tert-Butyl-5-((S)-1-phenyl-ethyl)-3a,5,6,6a-tetrahydro-1-oxa-4-thia-2,5-diaza-pentalene 4,4-dioxide(CAS DataBase Reference)
• NIST Chemistry Reference: (3aS,6aS)-3-tert-Butyl-5-((S)-1-phenyl-ethyl)-3a,5,6,6a-tetrahydro-1-oxa-4-thia-2,5-diaza-pentalene 4,4-dioxide(756895-88-2)
• EPA Substance Registry System: (3aS,6aS)-3-tert-Butyl-5-((S)-1-phenyl-ethyl)-3a,5,6,6a-tetrahydro-1-oxa-4-thia-2,5-diaza-pentalene 4,4-dioxide(756895-88-2)

Safety Data

• Hazardous Substances Data: 756895-88-2(Hazardous Substances Data)

Upstream product

• 27143-81-3 tert-butyl nitrile oxide 
• 2627-86-3 (S)-1-phenyl-ethylamine 
• 350506-88-6 2-((S)-1-Phenyl-ethyl)-2,3-dihydro-isothiazole 1,1-dioxide 

Relevant articles and documents

Synthesis of chiral sultams and their application as chiral auxiliaries in an asymmetric Diels-Alder reaction

A number of bicyclic chiral sultams were synthesized based on 1,3-dipolar cycloaddition reactions of nitrile oxides and nitrones with prop-1-ene-1,3- sultone. The corresponding N-enoyl sultams were prepared by acylation. Their relative effectiveness as new chiral auxiliaries in asymmetric synthesis was evaluated for the asymmetric Diels-Alder reactions with cyclopentadiene. Good chemical yield and excellent endo selectivity were observed. The relationship between the structure and their effectiveness in promoting asymmetric induction of the synthetic chiral sultams was investigated.