75700-89-9

Basic information

• Product Name: Os⁽²⁺⁾*C₆H₆*NH₂COC₅H₄N*2Cl^(1-)=[(C₆H₆)Os(NH₂COC₅H₄N)Cl₂]
• CAS NO: 75700-89-9
• Molecular Weight: 461.346
• Mol File: 75700-89-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Os⁽²⁺⁾*C₆H₆*NH₂COC₅H₄N*2Cl^(1-)=[(C₆H₆)Os(NH₂COC₅H₄N)Cl₂](CAS DataBase Reference)
• NIST Chemistry Reference: Os⁽²⁺⁾*C₆H₆*NH₂COC₅H₄N*2Cl^(1-)=[(C₆H₆)Os(NH₂COC₅H₄N)Cl₂](75700-89-9)
• EPA Substance Registry System: Os⁽²⁺⁾*C₆H₆*NH₂COC₅H₄N*2Cl^(1-)=[(C₆H₆)Os(NH₂COC₅H₄N)Cl₂](75700-89-9)

Safety Data

• Hazardous Substances Data: 75700-89-9(Hazardous Substances Data)

Upstream product

• 53886-43-4 {(η6-C6H6)OsCl2} 
• 1453-82-3 isonicotinamide 

Downstream Products

• 75716-24-4 Os⁽²⁺⁾*C₆H₆*2NH₂COC₅H₄N*Cl^(1-)*PF₆^(1-)=[(C₆H₆)Os(NH₂COC₅H₄N)2Cl]PF₆ 

Relevant articles and documents

Aquo chemistry of monoarene complexes of osmium(II) and ruthenium(II)

A number of derivatives of η-C6H6OsII (BzOsII) were prepared, exploiting the three positions not preempted by the arene ring and emphasizing ligands which are saturated. The species synthesized include [BzOs(NH3)3]2+, [BzOs(NH3)2Cl]+, and [BzOs(en)Cl]+. It was shown that a 2+ ion, presumably [BzOs(H2O)3]2+, is produced in an acidic solution of BzOsCl2 when Cl- is removed by Ag+. The determination of the acidity of the coordinated water for the aquo species is complicated by the condensation of the hydroxo form. However, [BzOs(en)H2O]2+ prepared from [BzOs(en)Cl]+ by adding Ag+ behaves normally, and the value of pKa was found to be 6.3 at 20°C; for [BzOs(NH3)2H2O]2+ it was found to be 6.4, and for [BzRu(en)H2O]2+ it is 7.9. The quotient governing association of Cl- with [BzOs(en)H2O]2+ was measured as 1.1 × 102. The acidity of the aquo ion and the stability of the chloride complex testify to the electron-withdrawing ability of the arene ring.