Cas 75701-52-9,[Fe(CNBu-t)3(1-4-η-C(NBu-t)=C(Ph)C(Ph)=C(=NBu-t))]*THF

75701-52-9

Post Buying Request

Basic information

Product Name: [Fe(CNBu-t)3(1-4-η-C(NBu-t)=C(Ph)C(Ph)=C(=NBu-t))]*THF
Synonyms:
CAS NO:75701-52-9
Molecular Formula:
Molecular Weight: 721.853
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: [Fe(CNBu-t)3(1-4-η-C(NBu-t)=C(Ph)C(Ph)=C(=NBu-t))]*THF(CAS DataBase Reference)
NIST Chemistry Reference: [Fe(CNBu-t)3(1-4-η-C(NBu-t)=C(Ph)C(Ph)=C(=NBu-t))]*THF(75701-52-9)
EPA Substance Registry System: [Fe(CNBu-t)3(1-4-η-C(NBu-t)=C(Ph)C(Ph)=C(=NBu-t))]*THF(75701-52-9)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 75701-52-9(Hazardous Substances Data)

Suppliers
Usage
Upstream product
Downstream Products
Article

75701-52-9 Suppliers

Recommended suppliers

75701-52-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 75701-52-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,5,7,0 and 1 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 75701-52:
(7*7)+(6*5)+(5*7)+(4*0)+(3*1)+(2*5)+(1*2)=129
129 % 10 = 9
So 75701-52-9 is a valid CAS Registry Number.

75701-52-9Upstream product

75701-52-9Downstream Products

75701-52-9Relevant academic research and scientific papers

Chemistry of Low-valent Metal Isocyanide Complexes. Part 2. Oxidative Reactions of Pentakis(t-butyl isocyanide)iron with Alkyl, Allyl, Benzyl, Fluoroalkyl and Pentafluorophenyl Halides, and with Trimethyloxonium Tetrafluoroborate and Diphenylacetylene. Evidence for Isocyanide Inserti...

Bassett, Jean-Marie,Green, Michael,Howard, Judith A. K.,Stone, F. Gordon A.

, p. 1779 - 1788 (1980)

Reaction of with MeI in thf (tetrahydrofuran) affords , whereas with diethyl ether as solvent the salt I is formed, which on dissolving in thf is transformed into the former product.Cationic complexes X are formed on reaction of in thf with allyl halides or benzyl bromide.However, EtI, EtBr, iPrI, and (Me3O)(BF4) afford η2-iminoacyl complexes .Reaction of with MeI or EtI gives FeI(CNC6H3Me-2,3)4>. n-Heptafluoropropyl iodide and bromopentafluorobenzene readily react with to give (CNtBu)4> and Br respectively.Diphenylacetylene reacts with to give >, which was structurally identified by a single-crystal X-ray diffraction study.The crystals are monoclinic, space group P21/c, Z = 4 in a unit cell of dimensions a = 9.724(4), b = 42.11(3), c = 11.330(4) Angstroem, β = 113.57(5) deg.The structure has been refined to R = 0.092 (R' = 0.123 for 4 327 reflections to 2.9/= 2θ /= 50.0 deg at 183 K.The dynamic behaviour of the complex in solution and its mode of formation are discussed.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 75701-52-9