Chemistry of Low-valent Metal Isocyanide Complexes. Part 2. Oxidative Reactions of Pentakis(t-butyl isocyanide)iron with Alkyl, Allyl, Benzyl, Fluoroalkyl and Pentafluorophenyl Halides, and with Trimethyloxonium Tetrafluoroborate and Diphenylacetylene. Evidence for Isocyanide Inserti...

DOI: 10.1039/DT9800001779

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1779 - 1788 (1980)

Update date:2022-08-02

Topics:

Authors:

Bassett, Jean-Marie

Green, Michael

Howard, Judith A. K.

Stone, F. Gordon A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9800001779

Reaction of with MeI in thf (tetrahydrofuran) affords , whereas with diethyl ether as solvent the salt I is formed, which on dissolving in thf is transformed into the former product.Cationic complexes X are formed on reaction of in thf with allyl halides or benzyl bromide.However, EtI, EtBr, iPrI, and (Me3O)(BF4) afford η²-iminoacyl complexes .Reaction of with MeI or EtI gives FeI(CNC6H3Me-2,3)4>. n-Heptafluoropropyl iodide and bromopentafluorobenzene readily react with to give (CNtBu)4> and Br respectively.Diphenylacetylene reacts with to give >, which was structurally identified by a single-crystal X-ray diffraction study.The crystals are monoclinic, space group P2₁/c, Z = 4 in a unit cell of dimensions a = 9.724(4), b = 42.11(3), c = 11.330(4) Angstroem, β = 113.57(5) deg.The structure has been refined to R = 0.092 (R' = 0.123 for 4 327 reflections to 2.9 View More

Full text of DOI:10.1039/DT9800001779

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Fe(CNBu-t)3(1-4-η-C(NBu-t)=C(Ph)C(Ph)=C(=NBu-t))]*THF

Cas No:75701-52-9

R&D Labs maybe for 75701-52-9

Taixing Joxin Bio-tec Co.,Ltd.

website:http://www.joxbio.com

Contact:86-523-87558858 87612088

Address:No.88, chengdong industrial park
NOVASYNCS CO., LTD

Contact:0512-63006287

Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
ClickChem Technology Co., Limited

Contact:+86-0310-6519966/0531-52893837

Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)

Contact:22-58516360

Address:tianjin

Relevant to this article

Hydrolysis of Esters and Amides in Strongly Basic Solution. Evidence for the Intermediacy of Carbanions

Doi:10.1021/jo00319a028
(1981)
A novel coordination mode of κ¹-N-Br-pyridylbenz-(imida, oxa or othia)-zole to Pt(ii): Synthesis, characterization, electrochemical and structural analysis

Doi:10.1039/c9ra01856e
(2019)
α-NITRO SULFONES. 2. CONVENIENT NEW SYNTHESIS AND SELECTED FUNCTIONAL GROUP TRANSFORMATIONS

Doi:10.1021/jo00317a023
(1981)
Doi:10.1021/jo00919a015
(1974)
Cycloaddition of Propargylic Amines and CO₂ by Ni@Pd Nanoclusters Confined Within Metal–Organic Framework Cavities in Aqueous Solution

Doi:10.1007/s10562-019-03072-3
(2020)
Total synthesis of rifamycins. II. Total synthesis of racemic rifamycin S

Doi:10.1021/ja00547a038
(1980)

Article Doi