75712-22-0

Basic information

• Product Name: 1-dodecenyl phenyl sulfide
• Synonyms: 1-dodecenyl phenyl sulfide
• CAS NO: 75712-22-0
• Molecular Weight: 276.486
• Mol File: 75712-22-0.mol

Chemical Properties

• CAS DataBase Reference: 1-dodecenyl phenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-dodecenyl phenyl sulfide(75712-22-0)
• EPA Substance Registry System: 1-dodecenyl phenyl sulfide(75712-22-0)

Safety Data

• Hazardous Substances Data: 75712-22-0(Hazardous Substances Data)

Upstream product

• 97-94-9 triethyl borane 
• 108-98-5 thiophenol 
• 104849-58-3 (E)-1-(triphenylstannyl)-1-dodecene 
• 92531-89-0 C₂₄H₃₄S₂ 
• 765-03-7 1-dodecyne 

Downstream Products

• 104849-71-0 1-triphenylstannyl-1-dodecene 
• 120677-81-8 2-triphenylgermyl-1-dodecyl phenyl sulfide 
• 92740-99-3 (E)-1-triphenylgermyl-1-dodecene 
• 92531-90-3 1-phenylsulfinyl-1-dodecene 

Relevant articles and documents

Synthesis of vinyl sulphides, azido sulphides, and olefins from β-hydroxy-sulphides

Vinyl sulphides, azido sulphides, and olefins have been prepared from β-hydroxy-sulphides via β-chloro-sulphides; the regio- and stereo-chemistry of these reactions is discussed.

Thiol mediated 5-(π-endo)ortho vinyl radical cyclizations

The radical reaction of benzenethiol with alkynes 1a-o carried out at 154 °C affords a mixture of thiol/alkyne adduct 3 and benzothiophene 5, deriving from vinyl radical intermediates 2 through hydrogen abstraction and 5-(π-endo)(orthocyclization onto the

Application of Free Radical Substitution Reaction into Interconversion of 1-Alkenylsulfides, 1-Alkenylgermanes, and 1-Alkenylstannanes

Treatment of 1-alkenylsulfides or 1-alkenylstannanes with Ph3GeH in the presence of Et3B provides 1-alkenyltriphenylgermanes in good yields. 1-Alkenylstannanes are converted into 1-alkenylsulfides easily with PhSH-Et3B, whereas 1-alkenyltriphenylgermanes are recovered unchanged upon treatment with Ph3SnH-Et3B or PhSH-Et3B.

Et3B Induced Radical Addition of Thiols to Acetylenes

Thiols added easily to acetylenic compounds in the presence of Et3B to give alkenyl sulfides in good yields.The reaction of acetylenes with 3-methyl-2-buten-1-thiol gave dihydrothiophene derivatives in one pot.

A New Synthesis of Olefins via the Elimination Reaction of β-Tributylstannyl Organosulfur Compounds

Organosulfur compounds on treatment with butyllithium in tetrahydrofuran followed by tributylstannylmethyl iodide 1 afforded olefins.The reaction was found to proceed via the destannylsulfurization of the initially formed β-stannyl organosulfur compounds.Thus, allyl 2-pyridyl sulfides 2 or allyl phenyl sulfones 12 were converted into 1,3-dienes 4.Compounds 13 and 15 were converted into the olefins 14 and 17.Furthermore, the reaction was applied to the synthesis of α-substituted vinyl sulfides 24 and allene 27.The stereochemistry of the double bond is discussed.Keywords - destannylsulfurization; allyl 2-pyridyl sulfide; allyl phenyl sulfone; synthesis of olefin; 1,3-diene; vinyl sulfide; β-tributylstannyl organosulfur compound.