75717-51-0Relevant academic research and scientific papers
Total synthesis of malyngamide M and isomalyngamide M
Chen, Jie,Shi, Zi-Fa,Zhou, Ling,Xie, An-Le,Cao, Xiao-Ping
experimental part, p. 3499 - 3507 (2010/06/17)
The stereoselective synthesis of malyngamide M (1) was accomplished in nine steps from o-cresol in 12% overall yield. The key steps involved the Wittig reaction of an α-NHBoc aryl ketone 4 for the introduction of vinyl chloride functionality, an amidation
TEMPLATE HOUBEN-HOESCH REACTION ON METAL PHENOLATES. SYNTHESIS OF AROMATIC KETONES, NITRILES AND AMIDES. CRYSTAL STRUCTURE OF DICHLORO-BORON
Bigi, Franca,Maggi, Raimondo,Sartori, Giovanni,Casnati, Giuseppe,Bocelli, Gabriele
, p. 283 - 289 (2007/10/02)
The crystal structure of dichloro-boron (6dx) establishes for the first time the coordination mechanism of the ortho-selective reaction of metal phenolates and nitriles.Crystal data: chemical formula C9H7BCl5NO2; a = 11.743(2), b = 13.390(2), c = 8.765(3) Angstroem, β = 99.71(2) deg; space group P21/n.Variously substituted aromatic ketones, nitriles and amides have been obtained in a "one-pot" reaction.
Process for production of 2-haloacetylphenols
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, (2008/06/13)
A new process for production of 2-haloacetylphenols having the general formula STR1 (wherein, Y is halogen atom; m is an integer of 0-2, X and n have the same meaning as mentioned below), which comprises reacting phenols having the general formula STR2 (w
