757242-11-8Relevant academic research and scientific papers
Mitsunobu glycosylation of nitrobenzenesulfonamides: Novel route to Amadori rearrangement products
Turner, John J.,Wilschut, Niels,Overkleeft, Herman S.,Klaffke, Werner,Van der Marel, Gijs A.,Van Boom, Jacques H.
, p. 7039 - 7042 (2007/10/03)
Amino-acid derived 2-nitrobenzenesulfonamides were successfully condensed under Mitsunobu conditions with 2,3,4,6-tetra-O-acetyl-D-glucose to afford the fully protected glucosylamines in excellent yield. Upon total deprotection, these compounds rearranged to provide the corresponding Amadori products in good overall yield.
