75730-02-8Relevant academic research and scientific papers
Cu-Catalyzed Carbonylative Silylation of Alkyl Halides: Efficient Access to Acylsilanes
Cheng, Li-Jie,Mankad, Neal P.
, p. 80 - 84 (2020)
A Cu-catalyzed carbonylative silylation of unactivated alkyl halides has been developed, enabling efficient synthesis of alkyl-substituted acylsilanes in high yield. A variety of functional groups are tolerated under the mild reaction conditions, and prim
The origin of β-silicon effect in electron-transfer reactions of silicon-substituted heteroatom compounds. electrochemical and theoretical studies
Yoshida, Jun-Ichi,Maekawa, Tsuyoshi,Murata, Toshiki,Matsunaga, Shin-Ichiro,Isoe, Sachihiko
, p. 1962 - 1970 (2007/10/02)
Silyl substitution at the carbon adjacent to the oxygen causes significant decrease in the electrochemical oxidation potentials of ethers and alcohols, and this effect strongly depends upon the geometry of the molecule. Two explanations are possible: (a)
THE PREPARATION OF α-HYDROXYORGANOSILANES FROM α-BORYLORGANOSILANE INTERMEDIATES
Larson, Gerald L.,Argueelles, Rafael,Rosario, Osvaldo,Sandoval, Sydia
, p. 15 - 24 (2007/10/02)
The generation of α-silyl-α-borylmethane derivatives as intermediates and their oxidation to α-hydroxyorganosilanes is reported.The formation of the intermediate α-silyl-α-borylmethane derivatives is via the type I transfer reaction of organoboranes with either (trimethylsilyl)bromomethyllithium and (phenyldimethylsilyl)chloromethyllithium in THF or in some cases hexane.
