75731-84-9Relevant academic research and scientific papers
Regio- and stereochemistry of dialkylcuprate additions to selected alkyldene oxiranes
Ziegler, Frederick E.,Cady, Michael A.
, p. 122 - 128 (2007/10/02)
The stereochemistry of the vinyloxiranes obtained by the treatment of several alkylidene cyclohexanones with dimethylsulfonium methylide is discussed.The structure and stereochemistry of the products produced by treatment of the vinyloxiranes with lithium
BIS-β,β'-CONJUGATE ADDITION
Smith, Amos B.,Wexler, Barry A.,Slade, Joel S.
, p. 3237 - 3240 (2007/10/02)
Addition of organocuprates to α,β-enones which possess on the β'-carbon a heteroatom substituent leads in good to excellent yield to β,β'-dialkylated ketones.This process is termed bis-β,β'-conjugate addition.
