7575-38-4Relevant articles and documents
Facile and efficient synthesis of ido-heptulosan via a strategy derived from Mo(VI)-catalysed reactions
Hricovi?niova?
, p. 751 - 754 (2001)
A simple and high-yielding method for the preparation of 2,7-anhydro-β-D-ido-heptulopyranose (IDO) is described. It utilises the ability of molybdate ions to create the conditions for the skeletal rearrangement in the molecule of 2-C-branched aldose. This evidence is used in the synthesis of IDO from 2-C-(hydroxymethyl)-2,3:5,6-di-O-isopropylidene-D-gulofuranose in one step. The title compound is obtained in 95percent yield.