75755-42-9

Upstream product

• 75755-40-7 2,2-dimethyl-3-(N-methyl-N-phenylamino)-2H-azirine 
• 123-06-8 Ethoxymethylenemalononitrile 
• 100-61-8 N-methylaniline 
• 58933-81-6 1-(1-chloro-2-methylprop-1-enyl)-N-methyl-N-phenylamine 
• 75755-45-2 N,2-dimethyl-N-phenylpropanethioamide 
• 55577-65-6 2,N-dimethyl-N-phenylpropanamide 

Relevant academic research and scientific papers

Photochemically Induced Reactions of 3-Amino-2H-azirines

Irradiation of 3-(N-methylanilino)-2H-azirines with a mercury low pressure lamp induces the cleavage of the C(2), C(3)-ring bond thus affording nitriliomethanide dipols, substituted by an amino group at C(1).Depending on the substitution pattern at C(3),

PHOTOCHEMICALLY INDUCED 1,3-DIPOLAR CYCLOADDITIONS OF 3-AMINO-2H-AZIRINES

Irradiation of 3-(N-methylanilino)-2H-azirines in dimethoxyethane solution in the presence of dipolarophiles leads to five-membered heterocycles in 40-60percent yield.A reation mechanism via splitting of the C(2),C(3)-bond and formation of a nitrilio methanide which then undergoes a thermal 1,3-dipolar cycloaddition is reasonable