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INFLUENCE DU GROUPEMENT METHOXYLE EN C-1 DANS L'ORIENTATION DE LA REDUCTION DES METHYL-HEXOPYRANOSID-2-ULOSES PAR LE BOROHYDRURE DE SODIUM
Saroli, Alfred,Descours, Denis,Carret, Genevieve,Anker, Daniel,Pacheco, Henri
, p. 71 - 82 (2007/10/02)
Methyl 3,4-dideoxy- and -3,4,6-trideoxyhexopyranosiduloses were synthesized by two reaction pathways.The α anomers were stereoselectively reduced by sodium borohydride to give compounds having the α-erythro configuration.Under the same conditions, the β a
