757959-57-2

Basic information

• Product Name: (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-6-[(R)-1-((E)-But-2-enoylamino)-2-hydroxy-ethyl]-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester
• Synonyms: (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-6-[(R)-1-((E)-But-2-enoylamino)-2-hydroxy-ethyl]-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester
• CAS NO: 757959-57-2
• Molecular Weight: 782.062
• Mol File: 757959-57-2.mol

Chemical Properties

• CAS DataBase Reference: (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-6-[(R)-1-((E)-But-2-enoylamino)-2-hydroxy-ethyl]-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-6-[(R)-1-((E)-But-2-enoylamino)-2-hydroxy-ethyl]-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester(757959-57-2)
• EPA Substance Registry System: (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-6-[(R)-1-((E)-But-2-enoylamino)-2-hydroxy-ethyl]-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester(757959-57-2)

Safety Data

• Hazardous Substances Data: 757959-57-2(Hazardous Substances Data)

Upstream product

• 757959-53-8 (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-1-hydroxy-2-triethylsilanyloxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 757959-55-0 (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-6-((R)-1-Amino-2-triethylsilanyloxy-ethyl)-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 757959-54-9 (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-6-((R)-1-Azido-2-triethylsilanyloxy-ethyl)-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 757959-52-7 (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-1,2-dihydroxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 757959-51-6 (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 757959-49-2 (Z)-4-{(2S,4R,6R)-6-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-hydroxy-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 757959-50-5 (Z)-4-{(2S,6S)-6-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-oxo-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 757959-41-4 (1S,5R,7S)-7-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-2,6-dioxa-bicyclo[3.3.1]nonan-3-one 
• 757959-46-9 {(2R,4R,6S)-4-Acetoxy-6-[(2R,4S,6R)-4-acetoxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-tetrahydro-pyran-2-yl}-acetic acid 
• 757959-45-8 Acetic acid (2R,4S,6R)-2-[(2S,4S,6S)-4-acetoxy-6-(2-hydroxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-4-yl ester 
• 757959-43-6 Acetic acid (2R,4S,6R)-2-((2S,4R,6R)-4-acetoxy-6-vinyl-tetrahydro-pyran-2-ylmethyl)-6-((S)-1,2-dihydroxy-ethyl)-tetrahydro-pyran-4-yl ester 
• 757959-44-7 Acetic acid (2R,4S,6R)-2-((2S,4R,6R)-4-acetoxy-6-vinyl-tetrahydro-pyran-2-ylmethyl)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-4-yl ester 
• 757959-47-0 (1S,5R,7S)-7-[(2S,4S,6R)-6-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-4-hydroxy-tetrahydro-pyran-2-ylmethyl]-2,6-dioxa-bicyclo[3.3.1]nonan-3-one 
• 757959-42-5 Acetic acid (2S,4R,6R)-2-((2R,4S,6R)-4-acetoxy-6-vinyl-tetrahydro-pyran-2-ylmethyl)-6-vinyl-tetrahydro-pyran-4-yl ester 

Relevant articles and documents

Synthesis of the C1-C17 segment of phorboxazole B

(Equation Presented) The C1-C17 bis-oxane subunit 22 of phorboxazole B is efficiently synthesized by exploiting differential reactivities between similar substituents on the hydropyran rings in 4. Selective dihydroxylation of the equatorial vinyl group, h