757959-41-4

Basic information

• Product Name: (1S,5R,7S)-7-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-2,6-dioxa-bicyclo[3.3.1]nonan-3-one
• Synonyms: (1S,5R,7S)-7-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-2,6-dioxa-bicyclo[3.3.1]nonan-3-one
• CAS NO: 757959-41-4
• Molecular Weight: 594.821
• Mol File: 757959-41-4.mol

Chemical Properties

• CAS DataBase Reference: (1S,5R,7S)-7-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-2,6-dioxa-bicyclo[3.3.1]nonan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,5R,7S)-7-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-2,6-dioxa-bicyclo[3.3.1]nonan-3-one(757959-41-4)
• EPA Substance Registry System: (1S,5R,7S)-7-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-2,6-dioxa-bicyclo[3.3.1]nonan-3-one(757959-41-4)

Safety Data

• Hazardous Substances Data: 757959-41-4(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 757959-47-0 (1S,5R,7S)-7-[(2S,4S,6R)-6-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-4-hydroxy-tetrahydro-pyran-2-ylmethyl]-2,6-dioxa-bicyclo[3.3.1]nonan-3-one 
• 620605-70-1 C₁₅H₂₄O₄ 
• 757959-42-5 Acetic acid (2S,4R,6R)-2-((2R,4S,6R)-4-acetoxy-6-vinyl-tetrahydro-pyran-2-ylmethyl)-6-vinyl-tetrahydro-pyran-4-yl ester 
• 757959-44-7 Acetic acid (2R,4S,6R)-2-((2S,4R,6R)-4-acetoxy-6-vinyl-tetrahydro-pyran-2-ylmethyl)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-4-yl ester 
• 757959-43-6 Acetic acid (2R,4S,6R)-2-((2S,4R,6R)-4-acetoxy-6-vinyl-tetrahydro-pyran-2-ylmethyl)-6-((S)-1,2-dihydroxy-ethyl)-tetrahydro-pyran-4-yl ester 
• 757959-45-8 Acetic acid (2R,4S,6R)-2-[(2S,4S,6S)-4-acetoxy-6-(2-hydroxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-4-yl ester 
• 757959-46-9 {(2R,4R,6S)-4-Acetoxy-6-[(2R,4S,6R)-4-acetoxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-tetrahydro-pyran-2-yl}-acetic acid 

Downstream Products

• 757959-49-2 (Z)-4-{(2S,4R,6R)-6-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-hydroxy-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 930807-74-2 C₃₄H₅₀O₇Si 
• 930807-79-7 C₄₄H₇₄Si₃O₆ 
• 930807-80-0 C₄₄H₇₃Si₃O₅N₃ 
• 930807-81-1 C₄₄H₇₅Si₃O₅N 
• 930807-75-3 C₄₀H₆₄Si₂O₇ 
• 930807-76-4 C₄₀H₆₂Si₂O₇ 
• 930807-77-5 C₄₁H₆₄Si₂O₆ 
• 930807-78-6 C₃₂H₄₆SiO₆ 
• 757959-50-5 (Z)-4-{(2S,6S)-6-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-oxo-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 757959-51-6 (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 757959-52-7 (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-1,2-dihydroxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 757959-57-2 (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-6-[(R)-1-((E)-But-2-enoylamino)-2-hydroxy-ethyl]-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 
• 757959-54-9 (Z)-4-{(2S,6R)-6-[(2R,4S,6R)-6-((R)-1-Azido-2-triethylsilanyloxy-ethyl)-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-but-2-enoic acid 4-methoxy-benzyl ester 

Relevant articles and documents

Synthesis of the C1-C17 segment of phorboxazole B

(Equation Presented) The C1-C17 bis-oxane subunit 22 of phorboxazole B is efficiently synthesized by exploiting differential reactivities between similar substituents on the hydropyran rings in 4. Selective dihydroxylation of the equatorial vinyl group, h