75802-05-0

Basic information

• Product Name: 3((C₆H₅CH₂)N(C₂H₅)3)⁽¹⁺⁾*(Rh₁₀P(CO)22)^(3-)=((C₆H₅CH₂)N(C₂H₅)3)3(Rh₁₀P(CO)22)
• Synonyms: 3((C₆H₅CH₂)N(C₂H₅)3)⁽¹⁺⁾*(Rh₁₀P(CO)22)^(3-)=((C₆H₅CH₂)N(C₂H₅)3)3(Rh₁₀P(CO)22)
• CAS NO: 75802-05-0
• Molecular Weight: 2253.23
• Mol File: 75802-05-0.mol

Chemical Properties

• CAS DataBase Reference: 3((C₆H₅CH₂)N(C₂H₅)3)⁽¹⁺⁾*(Rh₁₀P(CO)22)^(3-)=((C₆H₅CH₂)N(C₂H₅)3)3(Rh₁₀P(CO)22)(CAS DataBase Reference)
• NIST Chemistry Reference: 3((C₆H₅CH₂)N(C₂H₅)3)⁽¹⁺⁾*(Rh₁₀P(CO)22)^(3-)=((C₆H₅CH₂)N(C₂H₅)3)3(Rh₁₀P(CO)22)(75802-05-0)
• EPA Substance Registry System: 3((C₆H₅CH₂)N(C₂H₅)3)⁽¹⁺⁾*(Rh₁₀P(CO)22)^(3-)=((C₆H₅CH₂)N(C₂H₅)3)3(Rh₁₀P(CO)22)(75802-05-0)

Safety Data

• Hazardous Substances Data: 75802-05-0(Hazardous Substances Data)

Upstream product

• 56-37-1 N-benzyl-N,N,N-triethylammonium chloride 

Relevant articles and documents

[Rh10P(CO)22]3-. A transition-metal carbonyl cluster with a metal polyhedron based on the bicapped square antiprism as illustrated by the structural study of the benzyltriethylammonium salt

The reaction of Rh(CO)2acac with triphenylphosphine in the presence of cesium benzoate and cesium borohydride in tetraethylene glycol dimethyl ether solution resulted in the selective formation of [Rh10P(CO)22]3- (76% yield) after 4 h of contact time under 400 atm of carbon monoxide and hydrogen (CO:H2 = 1) at 140-160°C. The cluster has been isolated as the cesium and benzyltriethylammonium salts, both of which are stable to moisture and oxygen. These salts are soluble in polar organic solvents, e.g., acetone, but insoluble in solvents of lower polarity. The [C6H5CH2N(C2H5) 3]3[Rh10P(CO)22] complex has been characterized via a complete three-dimensional X-ray diffraction study. The complex crystallizes in the space group Cc with a = 25.011 (3) A?, b = 16.348 (4) A?, c = 18.267 (4) A?, α = γ = 90.0 (1)°, β = 101.47 (1)°, V = 7319.7 A?3, and p(calcd) = 2.045 g cm-3, for a molecular weight of 2253.24 and Z = 4. Diffraction data were collected with an Enraf-Nonius CAD 4 automated spectrometer using graphite-monochromatized Mo Kα radiation. The structure was solved by direct methods and refined by difference-Fourier and least-squares techniques. The rhodium cluster was found to have a 50:50 disorder when rotated 45° about the noncrystallographic fourfold axis in the cluster. All nonhydrogen atoms have been located and refined: final discrepancy indices are RF = 6.4% and RwF = 7.7% for 2700 reflections in the range of 0.5° a bicapped square antiprism with the phosphorus atom placed on the center of the cluster. This is the first instance in which this polyhedron has been reported for a transition-metal cluster. Average bonding distances for the anion are in the ranges Rh-Rh = 2.864-3007 A? and Rh-P = 2.446-3.012 A? with Rh-C and C-O distances similar to those usually observed for these complexes. 13C and 31P NMR results are interpreted as indicative of the fluxionality of the carbon monoxide and rhodium atoms cores, respectively. The reversibility of the reaction [Rh10P(CO)22]3- + 3CO ? [Rh9P(CO)21]2- + [Rh(CO)4]- has been established under ambient- and high-pressure conditions.