75806-06-3Relevant academic research and scientific papers
Ruthenium catalyzed oxidation of 1,2-diols to 1,2-diketones using bromamine-T as an oxidizing agent
Jain, Suman L.,Sharma, Vishal B.,Sain, Bir
, p. 465 - 469 (2007/10/03)
A variety of 1,2-diols were selectively oxidized to their corresponding 1,2-diketones with bromamine-T using RuCl3 · xH2O as catalyst in alkaline acetonitrile/ water (1:1) medium. The reaction was pH dependent (pH 8.4), and at higher pH the rate of the reaction decreased significantly. Copyright Taylor & Francis, Inc.
Methyltrioxorhenium catalyzed oxidation of 1,2-diols to 1,2-diketones using hydrogen peroxide as oxidant
Jain, Suman L.,Sharma, Vishal B.,Sain, Bir
, p. 1233 - 1235 (2007/10/03)
A variety of 1,2-diols were oxidized selectively to the corresponding 1,2-diketones by the dropwise addition of 30% aqueous hydrogen peroxide using methyltrioxorhenium as catalyst.
The Dithiole Series. Part 7. Synthesis of Compounds containing Condensed Ring Systems related to 1,6,6aλ4-Trithiapentalene.
Davidson, Stephen,Grinter, Trevor J.,Leaver, Derek,Steven, James H.
, p. 3172 - 3182 (2007/10/02)
1,8-Dichloro- and 1,8-dichloro-4,5-dinitro-anthraquinone react with sodium sulphide in boiling aqueous N,N-dimethylformamide to give, respectively, 5H-1,9,9aλ4-trithiapentalenoanthracen-5-one and its 4,6-diamino derivative.Under the same conditions, 1,4,5,8-tetrachloroanthraquinone gives 1,4,4aλ4,5,8,8aλ4-hexathiadipentalenoanthracene, and 2,2',6,6'-tetrachlorobenzophenone gives a low yield of 1,5,9,9aλ4-tetrapentalenoanthracene.
