75824-58-7

Upstream product

• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 4005-46-3 3-deoxy-1,2-O-isopropylidene-D-glucose 
• 98-59-9 p-toluenesulfonyl chloride 
• 75824-57-6 5,6-di-O-acetyl-1,2-O-isopropylidene-3-O-(methylthio)thiocarbonyl-α-D-glucofuranose 
• 74707-99-6 5,6-Di-O-acetyl-3-deoxy-1,2-O-isopropylidene-α-D-ribo-hexofuranose 
• 16667-96-2 1,2,5,6-di-O-isopropylidene-α-D-glucofuranose-3-O-(S-methylxanthate) 
• 72605-81-3 1,2-O-isopropylidene-3-O-(methylthio)thiocarbonyl-α-D-glucofuranose 

Downstream Products

• 1062488-70-3 6-O-toluoyl-3-deoxy-1,2-O-isopropylidene-β-L-lyxo-hexofuranose 
• 1062488-71-4 5,6-di-O-toluoyl-3-deoxy-1,2-O-isopropylidene-β-L-lyxo-hexofuranose 
• 20720-47-2 6-O-benzoyl-3-deoxy-1,2-O-isopropylidene-5-O-tosyl-α-D-ribo-hexofuranose 

Relevant academic research and scientific papers

Oxidation products of arachidonic acid I. The synthesis of methyl 8R, 11R, 15-trihydroxy-9S, 12-oxyeicosa-5Z, 13E-dienoate (19)

Diacetone glucose was converted in high yield to 3-deoxy-5-6-anhydro-1,2-0-isopropylidene-D-glucofuranose(3), which was transformed to title compound.3 Its mass spectrum confirms the structure of a naturally occurring oxidation product of arach

Synthesis of L-2′-deoxypentofuranonucleoside derivatives of thymine from D-glucose

Convergent synthesis of L-2′-deoxypentofuranonucleoside derivatives of thymine was carried out from D-glucose via 6-O-toluoyl-3-deoxy-1,2-O- isopropylidene-β-L-lyxo-hexofuranose as a key intermediate. Copyright Taylor & Francis Group, LLC.

Oxidation products of arachidonic acid II. The synthesis of methyl 8R,9S,11R-trihydroxy-5Z,12E,14Z-eicosatrienoate

A stereospecific total synthesis of the title compound, 37, starting from diacetone glucose (9), is described.Key intermediates in the synthesis are 3-deoxy-5,6-anhydro-1,2-O-isopropylidene-glucofuranose (15), obtained in 50percent yield fom 9, and methyl