75834-33-2

Upstream product

• 103-79-7 1-phenyl-acetone 
• 103-80-0 phenylacetyl chloride 
• 937-38-2 1-chloro-3-phenylpropan-2-one 

Downstream Products

• 82101-87-9 oxo-2-phenyl-3 propylphosphonate diethylique 
• 103-79-7 1-phenyl-acetone 

Relevant academic research and scientific papers

Direct α-iodination of ketones using iodine/SeO2

A satisfactory yield one-pot synthesis of various α-mono iodoketones 2 was achieved by iodination under oxidative conditions of ketones 1. The monoiodination of different aliphatic or cyclic ketones (1-tetralones) showed the quite general applicability of

Preparation of 1-aminoalkylphosphonic acids and 2-aminoalkylphosphonic acids by reductive amination of oxoalkylphosphonates

By reacting dialkyl 1-oxo- or 2-oxoalkylphosphonates with benzhydrylamine followed by reduction with triacetoxyborohydride and acid hydrolysis gave corresponding aminoalkylphosphonic acids with satisfactory yields. The use of benzylamine, α-methylbenzylamine and tritylamine was unsuccessful in the case of dialkyl 1-oxoalkylphosphonates whereas conversion of 2-oxoalkylphosphonates was also achieved although with lower yields.