75845-53-3Relevant academic research and scientific papers
PREPARATION OF THE SIXTEEN-ATOM RING CHELATES trans-tS(CH2)5-SBut>2>, M = Pd OR Pt: CRYSTAL STRUCTURE OF trans-tS(CH2)5-SBut>2>
Errington, John,McDonald, Walter S.,Shaw, Bernard L.
, p. 2309 - 2311 (1980)
Treatment of or t)2> with the new disulphide ButS(CH2)5SBut gives 16-atom ring chelates of the type trans-tS(CH2)5SBut>2>.Crystals of the compound with M = Pd are monoclinic, space group P21/n, with a = 17.359(4), b = 11.278(4), c = 23.080(6) Angstroem, β = 101.19(2) deg, and Z = 4.The 16-membered ring is rectangular with the bulky ButS groups forming the four corners, and it has the elongated-boat or 'barge' conformation.
