PREPARATION OF THE SIXTEEN-ATOM RING CHELATES trans-tS(CH2)5-SBut>2>, M = Pd OR Pt: CRYSTAL STRUCTURE OF trans-tS(CH2)5-SBut>2>

DOI: 10.1039/DT9800002309

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2309 - 2311 (1980)

Update date:2022-08-04

Topics:

Authors:

Errington, John

McDonald, Walter S.

Shaw, Bernard L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9800002309

Treatment of or t)2> with the new disulphide Bu^tS(CH2)5SBu^t gives 16-atom ring chelates of the type trans-tS(CH2)5SBu^t>2>.Crystals of the compound with M = Pd are monoclinic, space group P2₁/n, with a = 17.359(4), b = 11.278(4), c = 23.080(6) Angstroem, β = 101.19(2) deg, and Z = 4.The 16-membered ring is rectangular with the bulky Bu^tS groups forming the four corners, and it has the elongated-boat or 'barge' conformation.

Full text of DOI:10.1039/DT9800002309

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:trans-bis(μ-1,5-di-t-butylthiopentane-SS')-bis[dichloroplatinum(II)]*toluene

Cas No:75845-53-3

R&D Labs maybe for 75845-53-3

Changzhou Qidi Chemical Co., Ltd

website:http://www.czqdhg.com/

Contact:86-519-83382137

Address:128-1-16# HuaYuan Street,Hutang Town,Wujin District,Changzhou City,P.R.China.
Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang
Shanghai Egoal Chemical Co.,Ltd

Contact:+86-21-50333091

Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China

Relevant to this article

Doi:10.1021/jm00314a050
(1967)
Phosphorus-containing inhibitors of HMG-CoA reductase. 3. Synthesis of hydroxyphosphinyl-analogues of the mevinic acids

Doi:10.1016/S0040-4039(00)60052-7
(1993)
Reversal of Diastereoselectivity in the Addition of C-Nucleophiles to N-Trimethylsilyl Imines via Grignard Derived Organo Copper-Boron Trifluoride Reagents.

Doi:10.1016/0040-4039(93)88045-K
(1992)
Formation of Urea, Isourea, and Triazine Derivatives from Diisopropylcyanamide with Trifluoroacetic Anhydride and Trifluoromethanesulfonic Anhydride: Thermal Instability of Urea and Isourea Derivatives

Doi:10.1021/jo9710184
(1997)
Doi:10.1039/C19650000010
()
From Compounds to Materials: Heterodinuclear Complexes as Precursors in the Synthesis of Mixed Oxides; Crystal Structures of A)> and <A)NO3)(dmso)>2>*2dmso A = N,N'-ethylenebis(3-hydroxysalicylideneimine),

Doi:10.1039/DT9910002145
(1991)

Article Doi