PREPARATION OF THE SIXTEEN-ATOM RING CHELATES trans-tS(CH2)5-SBut>2>, M = Pd OR Pt: CRYSTAL STRUCTURE OF trans-tS(CH2)5-SBut>2>

DOI: 10.1039/DT9800002309

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2309 - 2311 (1980)

Update date:2022-08-04

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Authors:

Errington, John

McDonald, Walter S.

Shaw, Bernard L.

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Article abstract of DOI:10.1039/DT9800002309

Treatment of or t)2> with the new disulphide Bu^tS(CH2)5SBu^t gives 16-atom ring chelates of the type trans-tS(CH2)5SBu^t>2>.Crystals of the compound with M = Pd are monoclinic, space group P2₁/n, with a = 17.359(4), b = 11.278(4), c = 23.080(6) Angstroem, β = 101.19(2) deg, and Z = 4.The 16-membered ring is rectangular with the bulky Bu^tS groups forming the four corners, and it has the elongated-boat or 'barge' conformation.

Full text of DOI:10.1039/DT9800002309

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