758691-54-2

Upstream product

• 100-44-7 benzyl chloride 
• 148240-65-7 (1S,2S)-1,2-bis(2-methoxyphenyl)-1,2-ethanediamine 
• 578-57-4 2-bromoanisole 
• 693225-14-8 (1S,2S)-1,2-bis(2-methoxyphenyl)-N,N'-bis[(S)-1-phenylethyl]-1,2-ethanediamine 
• 58520-46-0 N,N'-(1,2-bis(2-methoxyphenyl)ethane-1,2-diyl)dibenzamide 
• 98-88-4 benzoyl chloride 

Relevant academic research and scientific papers

Enantioselective Reductive Coupling of Imines Templated by Chiral Diboron

We herein report a general, practical, and highly efficient method for asymmetric synthesis of a wide range of chiral vicinal diamines via reductive coupling of imines templated by chiral diboron. The protocol features high enantioselectivity and stereospecificity, mild reaction conditions, simple operating procedures, use of readily available starting materials, and a broad substrate scope. The method signifies the generality of diboron-enabled [3,3]-sigmatropic rearrangement.

New chiral 1,2-diamines and their use in zinc-catalyzed asymmetric hydrosilylation of acetophenone

The preparation of two new series of chiral 1,2-diamines and their use in the [ZnR2-diamine]-catalyzed asymmetric hydrosilylation of acetophenone with poly(methylhydrosiloxane) (PMHS) in an aprotic medium is reported. The effect of structural m