75924-54-8Relevant academic research and scientific papers
Synthesis of (±)-trans-2,5-diisopropylborolane
Laschober, Gerhard,Zorzi, Massimo,Hodgetts, Kevin J.
, p. 244 - 252 (2007/10/03)
The cyclic hydroboration of 2,7-dimethyl-2,6-octadiene (6) was studied. It was found that the stereochemical outcome of the reaction was dependent upon the solvent, temperature, time and the nature of the borane reagent. Pure racemic trans-2,5-diisopropyl
Remote Stereocontrol by utilizing Intramolecular Carbonyl Reduction with Boranes
Harada, Toshiro,Matsuda, Yasuhiro,Imanaka, Satoru,Oku, Akira
, p. 1641 - 1643 (2007/10/02)
A simple and efficient method for the remote (1,4- and/or 1,5-) stereocontrol was realized by utilizing an intramolecular carbonyl reduction with ThexBH2 (Thex = 1,1,2-trimethylpropyl).
