75945-53-8

Basic information

• Product Name: 3-Butoxyacryloyl chloride
• Synonyms: 3-Butoxyacryloyl chloride;3-butoxyprop-2-enoyl chloride
• CAS NO: 75945-53-8
• Molecular Formula: C7H11ClO2
• Molecular Weight: 162.61
• Mol File: 75945-53-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Butoxyacryloyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Butoxyacryloyl chloride(75945-53-8)
• EPA Substance Registry System: 3-Butoxyacryloyl chloride(75945-53-8)

Safety Data

• Hazardous Substances Data: 75945-53-8(Hazardous Substances Data)

Upstream product

• 75-44-5 phosgene 
• 111-34-2 -butyl vinyl ether 
• 109317-70-6 trans-β-n-Butoxyacrylic acid 

Relevant articles and documents

Use of the curtius rearrangement of acryloyl azides in the synthesis of 3,5-disubstituted pyridines: Mechanistic studies

A series of disubstituted pyridine derivatives was synthesized from the corresponding acryloyl azides by acetic acid-promoted cycloaddition. This represents a novel and convenient synthetic approach to the symmetric 3,5-disubstituted pyridines. The nature of the substituent on the double bond and the utilized solvent were found to be crucial to the yield of pyridines. The reactivity of the acid-promoted cycloaddition increases with the presence of aryl groups, such as phenyl and pyridinyl. We also explored the comprehensive mechanism by the acid-promoted cycloaddition of 13C-labeled cinnamoyl azide. The symmetric 3,5-disubstituted pyridines were synthesized from acryloyl azides by acetic acid-promoted trimolecular condensation.