75988-01-1Relevant academic research and scientific papers
A mild and convenient synthesis of functionalized methyl triflones and vinyl triflones
Mahadevan, Anu,Fuchs
, p. 6025 - 6028 (2007/10/02)
A general route for the synthesis of methyl triflone derivatives utilizing triflic anhydride is described. Stereoselective synthesis of E-vinyl and dienyl triflones has been accomplished by the Peterson olefination reaction of α-silyl triflone anions.
Synthesis and reactions of functionalized perfluoroalkyl sulfones
Hanack,Bailer,Hackenberg,Subramanian
, p. 1205 - 1208 (2007/10/02)
The hitherto unknown 2-aryl-1-(perfluoroalkanesulfonyl)acrylonitriles 9(R(F) = CF3, C4F9) were prepared by Knoevenagel condensation of (perfluoroalkanesulfonyl)acetonitriles 7 with aromatic aldehydes. The nitriles 7 were p
Perfluoroalkylsulfonylacetic and perfluoroalkylsulfonylmalonic esters
Ogoiko, P. I.,Nazaretyan, V. P.,Il'chenko, A. Ya.,Yagupol'skii, L. M.
, p. 1200 - 1203 (2007/10/02)
A preparetive method was developed for the synthesis of perfluoroalkylsulfonylacetic and perfluoroalkylsulfonylmalonic esters.From the latter stable perfluoroalkylsulfonyl(ethoxycarbonyl)ketenes were obtained. β,β-Disubstituted p-dimethylaminostyrenes were synthesized, and the effect of strong electron-withdrawing substituents on their color was investigated.
