7599-18-0

Basic information

• Product Name: 2-(hydroxymethyl)-6-{[(6E)-2,3,4-trihydroxy-5,6-bis(2-phenylhydrazinylidene)hexyl]oxy}tetrahydro-2H-pyran-3,4,5-triol (non-preferred name)
• CAS NO: 7599-18-0
• Molecular Formula: C₂₄H₃₂N₄O₉
• Molecular Weight: 520.5323
• Mol File: 7599-18-0.mol

Chemical Properties

• Boiling Point: 843.829°C at 760 mmHg
• Flash Point: 464.131°C
• Density: 1.506g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.653
• CAS DataBase Reference: 2-(hydroxymethyl)-6-{[(6E)-2,3,4-trihydroxy-5,6-bis(2-phenylhydrazinylidene)hexyl]oxy}tetrahydro-2H-pyran-3,4,5-triol (non-preferred name)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(hydroxymethyl)-6-{[(6E)-2,3,4-trihydroxy-5,6-bis(2-phenylhydrazinylidene)hexyl]oxy}tetrahydro-2H-pyran-3,4,5-triol (non-preferred name)(7599-18-0)
• EPA Substance Registry System: 2-(hydroxymethyl)-6-{[(6E)-2,3,4-trihydroxy-5,6-bis(2-phenylhydrazinylidene)hexyl]oxy}tetrahydro-2H-pyran-3,4,5-triol (non-preferred name)(7599-18-0)

Safety Data

• Hazardous Substances Data: 7599-18-0(Hazardous Substances Data)

Usage

Hydroxymethyl group

A group consisting of a carbon atom bonded to a hydroxyl group (-OH) and a methyl group (-CH3).

Tetrahydropyran ring

A six-membered cyclic structure consisting of four carbon atoms and two oxygen atoms, with the carbon atoms having hybridization between sp3 and sp2.

Hydroxyl groups

Functional groups consisting of an oxygen atom bonded to a hydrogen atom (-OH), which are capable of forming hydrogen bonds.

Carbon-carbon double bonds

C=C bonds in the long chain, which can participate in addition reactions and can influence the chemical reactivity of the molecule.

Phenylhydrazinylidene groups

Groups consisting of a phenyl ring attached to a hydrazinylidene group (-NH-N=CH-), which can act as chelating agents and have potential applications in medicinal chemistry.

Complex structure

The presence of multiple functional groups and a long chain with carbon-carbon double bonds and phenylhydrazinylidene groups makes the compound complex and potentially interesting for further research.

Upstream product

• 5077-31-6 6-O-β-galactopyranosyl-D-galactose 
• 5239-08-7 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1-> 6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 
• 3068-32-4 1-bromo-1-deoxy-2,3,4,6-tetra-O-acetyl-a-D-galactopyranoside 
• 59-88-1 phenylhydrazine hydrochloride 
• 100-63-0 phenylhydrazine 
• 499-40-1 α-(1,6)-mannobiose 
• 69685-27-4 1,2,3,4-tetra-O-acetyl-6-O-(tetra-O-acetyl-α-D-mannopyranosyl)-β-D-mannopyranose 
• 28154-37-2 1,2,3,4-tetra-O-acetyl-β-D-mannopyranose 
• 13242-53-0 acetobromomannose 
• 83-87-4 β-D-mannopyranose pentaacetate 
• 497-84-7 Isomaltulose 

Downstream Products

• 35426-99-4 D-(1R)-O⁴-β-D-glucopyranosyl-1-(2-phenyl-2H-[1,2,3]triazol-4-yl)-erythritol 
• 35426-99-4 D-(1R)-O⁴-α-D-glucopyranosyl-1-(2-phenyl-2H-[1,2,3]triazol-4-yl)-erythritol 
• 35426-99-4 L_r-3c_F-α-D-galactopyranosyloxy-4cat_F-4-(2-phenyl-2H-[1,2,3]triazol-4-yl)-butane-1,2r_F,4t_F-triol 
• 3082-94-8 Acetic acid (2S,3R,4S,5R,6R)-3,5-diacetoxy-2-{(S)-2-acetoxy-2-[5-(acetyl-phenyl-hydrazonomethyl)-2-phenyl-2H-pyrazol-3-yl]-ethoxy}-6-acetoxymethyl-tetrahydro-pyran-4-yl ester 
• 361389-99-3 6,7-dichloro-2-[(1'R,2'S,3'R)-40-(α-D-glucopyranosyloxy)-1',2',3'-trihydroxybutyl]quinoxaline 

Relevant articles and documents

Hydrophilically functionalized pyrazoles from sugars

An effective and convenient protocol has been developed for the conversion of D-glucose and 6-O-α-D-glucopyranosyl-D-fructose (palatinose, isomaltulose) into 5-[(1'S)-1','2/-dihydroxyethyl]-1-phenylpyrazole-3-carboxaldehyde (4) and 5-[(1'S)-2-(α-D-glucopyranosyloxy)-1-hydroxethyl])-1-phenylpyrazole-3 -carboxaldehyde (5), key steps being the acetic anhydride-promoted dehydrative cyclization of the respective phenylosazones, and subsequent liberation of the N-acetylphenylhydrazone-blocked aldehyde function. Exploitation of the ensuing chemistry of 4 and 5 led to a variety of pyrazole building blocks with a diverse level of hydrophilic substituents (hydroxymethyl, dihydroxyethyl or glucosyl residues) and useful functional groups, such as chloro, cyano, aminomethyl, vinyl and acryloyl moieties.