76002-35-2Relevant academic research and scientific papers
Preparation and reactivity of phenyltelluroalkylphosphine oxides. Vinylic tellurides
Silveira, Claudio C.,Braga, Antonio L.,Guadagnin, Rafael C.
, p. 5703 - 5705 (2003)
Phenyltelluromethyldiphenylphosphine oxide was prepared by the reaction of methyldiphenylphosphine oxide with base and PhTeBr. The telluromethylphosphine oxide reacts with aldehydes and ketones to give the corresponding vinylic tellurides, with preferential E stereochemistry for aryl aldehydes and Z for alkyl aldehydes.
STARKE ERLEICHTERUNG DER CARBONYLOLEFINIERUNG MIT ORGANOSCHWERMETALLREAGENZIEN DURCH EINE DIPHENYLPHOSPHORYLGRUPPE IM REAGENZ
Tilhard, Hans-Joachim,Ahlers, Holger,Kauffmann, Thomas
, p. 2803 - 2806 (2007/10/02)
Carbonyl olefination with a lithiomethane, having besides the group -P(O)Ph2 at the methane C-atom an organo-heavy-metal group, occurs at low temperatures to give exclusively diphenylphosphoryl substituted olefins.
