76010-85-0

Basic information

• Product Name: 2-(Chloro-naphthalen-1-yl-methyl)-tetrahydro-furan
• CAS NO: 76010-85-0
• Molecular Weight: 246.737
• Mol File: 76010-85-0.mol

Chemical Properties

• CAS DataBase Reference: 2-(Chloro-naphthalen-1-yl-methyl)-tetrahydro-furan(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Chloro-naphthalen-1-yl-methyl)-tetrahydro-furan(76010-85-0)
• EPA Substance Registry System: 2-(Chloro-naphthalen-1-yl-methyl)-tetrahydro-furan(76010-85-0)

Safety Data

• Hazardous Substances Data: 76010-85-0(Hazardous Substances Data)

Upstream product

• 60096-40-4 7,7-dichloro-5-bromobenzobicyclo<4.1.0>heptane 
• 109-99-9 tetrahydrofuran 

Relevant articles and documents

Generation of Bicycloheptatrienes

Derivatives of bicycloheptatriene have been generated in solution by the base-induced dehydrochlorination of gem-dichlorocyclopropanes.Reaction of 7,7-dichlorodibenzobicycloheptane with potassium tert-butoxide in tetrahydrofuran at 0 deg C gives mainly products derived from solvent incorporation by carbene insertion.Evidence that the carbene results from rearrangement of the bicycloheptatriene derives from the successful interception of the bicycloheptatriene with nucleophile (MeS-). endo-7-Chlorodibenzobicycloheptane failed to reactwith potassium tert-butoxide in tetrahydrofuran.Generation of benzobicycloheptatrienes was also accomplished via the base-induced dehydrochlorination of gem-dichlorocyclopropanes. 1-Methylbenzobicycloheptatriene gives products derived from multiple carbene-carbene rearrangements.In contrast, nonannelated methylbicycloheptatrienes generated by the dehydrochlorination route give only carbene-derived products resulting from the initially produced bicycloheptatriene.