76017-71-5Relevant academic research and scientific papers
Kinetics and mechanism of nucleophilic displacements with heterocycles as leaving groups. Part 23. Studies at the borderlines between reactions proceeding (i) via free carbocations, (ii) via rate-determining formation of ion-molecule pairs, and (iii) via rate-determining nucleophilic ...
Katritzky, Alan R.,Brycki, Bogumil
, p. 1161 - 1169 (2007/10/02)
Evidenece is presented to demonstrate that at the borderline between first order reaction via the formation of free carbocations, both mechanism proceed independently, without merging.Similarly at the borderline between first-order (rate determining formation) and second-order (rate-determining nucleophilic attack) rections of intimate ion-molecule pairs, both reactions again proceed independently.
The Preparation of Pyridiniums from Pyryliums
Katritzky, Alan R.,Lloyd, Jeremy M.,Patel, Ranjan C.
, p. 117 - 124 (2007/10/02)
Mild preparative conditions are described for the reaction of primary alkyl-, secondary alkyl-, and aryl-primary amines (including weakly basic amines) with pyryliums (including those with bulky α-substituents).Conditions were optimized by 13C n.m.r. stud
The Preparation of 2,4,6-Triphenylpyrylium Trifluoromethanesulphonate, Fluorosulphonate, Ethoxysulphonate, Naphthalene-2-sulphonate, Stannochloride, Trichloroacetate, and Trifluoroacetate and other Pyrylium Trifluoromethanesulphonates and their Reactions
Katritzky, Alan R.,El-Mowafy, Azzahra M.,Marzorati, Liliana,Patel, Ranjan C.,Thind, Sukhpal S.
, p. 4001 - 4030 (2007/10/02)
The title pyrylium salts are all readily prepared in high yield from 1,3,5-triphenylpent-2-ene-1,5-dione.Amines react with the trifluoromethanesulphonate, naphthalene-2-sulphonate, and trifluoroacetate to give the corresponding pyridinium salts in high yi
