76030-62-1Relevant academic research and scientific papers
A MODEL FOR FAD-CONTAINING MONOOXYGENASE : THE OXYDATION OF THIOANISOLE DERIVATES BY AN ISOALLOXAZINE HYDROPEROXIDE
Miller, Audrey
, p. 753 - 756 (2007/10/02)
A 4a-isoalloxazine hydroperoxide oxidizes thioanisole derivates to corresponding sulfoxides by a mechanism which involves nucleophilic attack of sulfur on electrophilic oxygen.
Products of the Decomposition of the Anion of a 4a-Hydroperoxyisoalloxazine Hindered in the 9a and 10a Positions
Bruice, Thomas C.,Miller, Audrey
, p. 693 - 694 (2007/10/02)
Products formed from the decomposition of the 4a-peroxy-anion of the flavin (1d) are only accountable through reactions involving the 4a-hydroperoxide anion; kinetic and product studies both argue against the involvement of a 4a -> 10a peroxy-anion migration.
