76071-79-9Relevant academic research and scientific papers
Ranging correlated motion (1.5 nm) of two coaxially arranged rotors mediated by helix inversion of a supramolecular transmitter
Hiraoka, Shuichi,Okuno, Erika,Tanaka, Takaaki,Shiro, Motoo,Shionoya, Mitsuhiko
supporting information; experimental part, p. 9089 - 9098 (2009/02/03)
For a long-range transmission of motion between two movable parts apart from each other, transmitters that can precisely correlate these two motions should be properly incorporated into the system. However, such a motional relay is yet to be realized in a
Electrostatically controlled hierarchical arrangement of monocationic silver(I) and dicationic mercury(II) ions between disk-shaped template ligands
Hiraoka, Shuichi,Tanaka, Takaaki,Shionoya, Mitsuhiko
, p. 13038 - 13039 (2008/02/05)
This paper describes hierarchical arrangement of three Ag+ and three Hg2+ ions using two disk-shaped hexa-monodentate template ligands in which three oxazolyl rings are arranged each on the two concentric circles. The hierarchical manner of ligand arrangement allows the selective binding of monocationic Ag+ and dicationic Hg2+ ions to the inner first and the outer second generation coordination sites, respectively. This hierarchically well-balanced metal assembly should arise primarily from a minimized electrostatic repulsion between positively charged six metal ions arranged within the heteronuclear complex. Copyright
α-ACETYLENIC ETHYLENEIMIDES AND THEIR REACTIONS WITH AMINES
Eremeev, A. V.,Tikhomirov, D. A.,Shubina, Yu. V.
, p. 825 - 828 (2007/10/02)
The reaction of aziridines with phenyl and p-chlorophenylpropiolyl chlorides at -30 to 60 deg C leads only to 1,2-addition products, viz., α-acetylenic ethyleneimides, or their isomerization products, viz., 2-ethynyl-substituted 2-oxazolines.Reactions wit
