760947-34-0

Basic information

• Product Name: [(N-isopropyl-2-(isopropylamino)troponiminato)Zn-OPh]2
• CAS NO: 760947-34-0
• Molecular Weight: 723.605
• Mol File: 760947-34-0.mol

Chemical Properties

• CAS DataBase Reference: [(N-isopropyl-2-(isopropylamino)troponiminato)Zn-OPh]2(CAS DataBase Reference)
• NIST Chemistry Reference: [(N-isopropyl-2-(isopropylamino)troponiminato)Zn-OPh]2(760947-34-0)
• EPA Substance Registry System: [(N-isopropyl-2-(isopropylamino)troponiminato)Zn-OPh]2(760947-34-0)

Safety Data

• Hazardous Substances Data: 760947-34-0(Hazardous Substances Data)

Upstream product

• 3337-06-2 1-isopropylamino-7-isopropylimino-1,3,5-cycloheptatriene 
• 544-97-8 dimethyl zinc(II) 
• 108-95-2 phenol 

Relevant articles and documents

Aminotroponiminate alkyl and alkoxide complexes of zinc

Reaction of {(iPr)2ATI}H ((iPr)2 ATI=N-isopropyl-2-(isopropylamino)troponiminate) with dimethyl zinc in toluene afforded the methyl complex [{(iPr)2ATI} Zn-Me]. Subsequent reaction of [{(iPr)2ATI}Zn-Me] with different alcohols gave the alkoxide complexes [{(iPr)2ATI} Zn-OR]2(R = iPr, tBu, Ph). These compounds, which were investigated by single crystal X-ray diffraction, are dimeric in the solid-state. In the solid-state the metal centers are bridged symmetrically by two μ-oxygen atoms, thus a flat Zn-O-Zn′-′ plane is observed. [{(iPr)2ATI}Zn-OR] 2 were used as catalysts for the copolymerization experiments of epoxides and CO2.