760980-83-4

Basic information

• Product Name: (Z)-1-bromo-3-(prop-1-en-1-yloxy)benzene
• CAS NO: 760980-83-4
• Molecular Weight: 213.074
• Mol File: 760980-83-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-1-bromo-3-(prop-1-en-1-yloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-bromo-3-(prop-1-en-1-yloxy)benzene(760980-83-4)
• EPA Substance Registry System: (Z)-1-bromo-3-(prop-1-en-1-yloxy)benzene(760980-83-4)

Safety Data

• Hazardous Substances Data: 760980-83-4(Hazardous Substances Data)

Upstream product

• 41388-50-5 1-(allyloxy)-3-bromobenzene 
• 591-20-8 3-Bromophenol 

Relevant articles and documents

Specific Z-Selectivity in the Oxidative Isomerization of Allyl Ethers to Generate Geometrically Defined Z-Enol Ethers Using a Cobalt(II)(salen) Complex Catalyst

Enol ether structural motifs exist in many highly oxygenated biologically active natural products and pharmaceuticals. The synthesis of the geometrically less stable Z-enol ethers is challenging. An efficient Z-selective oxidative isomerization process of allyl ethers catalyzed by a cobalt(II) (salen) complex using N-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate (Me3NFPY?OTf) as an oxidant has been developed. Thermodynamically less stable Z-enol ethers were prepared in excellent yields with high geometric control. This methodology also demonstrates the effectiveness in controlling the Z-selective isomerization reaction of diallyl ethers at room temperature. This catalytic system provides an alternative pathway to extend the traditional reductive isomerization of allyl ethers.