76101-83-2Relevant articles and documents
Synthesis of α- and β-D,L-ribo-carbahex-2-ulofuranose
Marschner,Penn,Griengl
, p. 5067 - 5078 (2007/10/02)
Both α- and β-D,L-ribo-carbahex-2-ulofuranose have been synthesized in racemic form starting from norbornen-2-one. In the course of the synthesis the reaction of sulfur ylides with α-alkoxyketones took an unexpected stereochemical pathway.
Efficient Stereocontrolled Total Syntheses of Racemic and Natural Brefeldin-A
Drian, Claude Le,Greene, Andrew E.
, p. 5473 - 5483 (2007/10/02)
Brefeldin-A, an antiobiotic fungal metabolite, has been obtained in both racemic and natural forms through a direct approach that employs norbornenone and 6-heptyn-2-ol as the basic starting materials.