144874-55-5Relevant articles and documents
Synthesis of α- and β-D,L-ribo-carbahex-2-ulofuranose
Marschner,Penn,Griengl
, p. 5067 - 5078 (2007/10/02)
Both α- and β-D,L-ribo-carbahex-2-ulofuranose have been synthesized in racemic form starting from norbornen-2-one. In the course of the synthesis the reaction of sulfur ylides with α-alkoxyketones took an unexpected stereochemical pathway.
Synthesis of pseudo-Ribofuranoses by Stereocontrolled Reactions on 4-Hydroxycyclopent-2-enylmethanol Derivatives
Shoberu, Karoline A.,Roberts, Stanley M.
, p. 2419 - 2426 (2007/10/02)
The diol 3 is a major product formed from a Prins reaction on cyclopentadiene and was readily converted into the derivatives 4-7.The latter compounds were obtained in states of high optical purity by using both enzyme-catalysed hydrolysis and esterificati
