76119-08-9

Basic information

• Product Name: (E)-(3-((3-methylbut-2-en-1-yl)oxy)prop-1-en-1-yl)benzene
• Synonyms: (E)-(3-((3-methylbut-2-en-1-yl)oxy)prop-1-en-1-yl)benzene
• CAS NO: 76119-08-9
• Molecular Weight: 202.296
• Mol File: 76119-08-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (E)-(3-((3-methylbut-2-en-1-yl)oxy)prop-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(3-((3-methylbut-2-en-1-yl)oxy)prop-1-en-1-yl)benzene(76119-08-9)
• EPA Substance Registry System: (E)-(3-((3-methylbut-2-en-1-yl)oxy)prop-1-en-1-yl)benzene(76119-08-9)

Safety Data

• Hazardous Substances Data: 76119-08-9(Hazardous Substances Data)

Upstream product

• 104-54-1 3-Phenylpropenol 
• 870-63-3 prenyl bromide 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 2327-99-3 1-phenylpropadiene 
• 556-82-1 3-methyl-2-buten-1-ol 

Downstream Products

• 76119-07-8 3-methoxy-4,4-dimethyl-1-phenylhexa-1,5-diene 
• 108970-09-8 (E)-3-Hydroxy-4,4-dimethyl-1-phenyl-1,5-hexadiene 

Relevant articles and documents

Pd(O)-PhCOOH catalyzed addition of oxygen pronucleophiles to allenes and internal alkynes

We have developed a catalytic system that enables the addition of alcohols to allenes using a combination of 5 mol% Pd(PPh3)4 and 10 mol% benzoic acid. Likewise, the addition reaction of carboxylic acids to alkynes is described. In all cases the reaction proceeded well, giving the corresponding allylation products in good-to-high yields with high regio- and stereoselectivities.

Tailoring flavins for visible light photocatalysis: organocatalytic [2+2] cycloadditions mediated by a flavin derivative and visible light

A new application of flavin derivatives in visible light photocatalysis was found. 1-Butyl-7,8-dimethoxy-3-methylalloxazine, when irradiated by visible light, was shown to allow an efficient cyclobutane ring formation via an intramolecular [2+2] cycloaddition of both styrene dienes, considered as electron-rich substrates, and electron-poor bis(arylenones), presumably proceeding via an energy transfer mechanism.

Base Catalysed Rearrangements involving Ylide Intermediates. Part 4. Sigmatropic Rearrangements of 4-Dimethylaminobutenes and Sigmatropic Rearrangements of 3-Dimethylaminohexa-1,5-dienes

The sighmatropic rearrangement (11) -> (12) of the 9-dimethylamino-9-(1-phenylallyl)fluorene is a stereoselective process (84:16) at 170 deg C.Analogous rearrangements (16) -> (17) of the fluorene derivatives show that the reaction rate is increased by electron donating 9-substituents in the order O- > NMe2 > OMe.Similar substituent effects are observed for the Cope rearrangement (25) -> (26) of hexa-1,5-dienes. 4-Phenyl, 4,4-dimethyl, and 3-dimethylamino substituents are particularly effective in accelerating the rate of the rearrangement (25) -> (26).