761402-04-4

Basic information

• Product Name: 1-[(E)-3-(Methyl-diphenyl-silanyl)-allyl]-piperidin-2-one
• Synonyms: 1-[(E)-3-(Methyl-diphenyl-silanyl)-allyl]-piperidin-2-one
• CAS NO: 761402-04-4
• Molecular Weight: 335.521
• Mol File: 761402-04-4.mol

Chemical Properties

• CAS DataBase Reference: 1-[(E)-3-(Methyl-diphenyl-silanyl)-allyl]-piperidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[(E)-3-(Methyl-diphenyl-silanyl)-allyl]-piperidin-2-one(761402-04-4)
• EPA Substance Registry System: 1-[(E)-3-(Methyl-diphenyl-silanyl)-allyl]-piperidin-2-one(761402-04-4)

Safety Data

• Hazardous Substances Data: 761402-04-4(Hazardous Substances Data)

Upstream product

• 144-79-6 chloromethyldiphenylsilane 
• 761401-99-4 But-3-enoic acid allyl-[(E)-3-(methyl-diphenyl-silanyl)-allyl]-amide 
• 756436-57-4 3-(methyldiphenylsilyl)-2-propyn-1-ol 
• 761401-96-1 3E-(methyldiphenylsilyl)-2-propenal 
• 101844-25-1 3E-(methyldiphenylsilyl)-2-propen-1-ol 
• 761401-97-2 Allyl-[(E)-3-(methyl-diphenyl-silanyl)-allyl]-amine 

Relevant articles and documents

ROMPgel-supported tris(triphenylphosphine)rhodium(I) chloride: A selective hydrogenation catalyst for parallel synthesis

ROMPgel-supported tris(triphenylphosphine)rhodium(I) chloride has been prepared and the immobilised catalyst has been effectively employed in selective hydrogenations of a variety of alkenes and terminal alkynes.

Directed ring-closing metathesis of trienes by silyl substitution

A synthetic strategy for 'disarming' a terminal alkene by substitution with a bulky silyl blocking group has been developed. In a series of model studies, sequential selective ring-closing metathesis of trienes followed by selective mono-hydrogenation of the resulting diene is described. The bulky silylated alkene is activated for a subsequent cross-metathesis reaction with a range of diverse alkenes by protodesilylation.