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OXYDATIVE ADDITION VON α,ω-DIHALOGENIDEN AN BIS(TRIPHENYLPHOSPHIN)-ETHEN-NICKEL
Hipler, B.,Uhlig, E.
, p. C27 - C30 (1980)
The oxidative addition of α,α'-dichloro-p-xylene to (Ph3P)2Ni(C2H4) affords the blue violet binuclear nickel(II) complex (Ph3P)2ClNiCH2C6H4CH2NiCl(PPh3)2.On the other hand no organonickel compound, but (Ph3P)2NiBr2 and 1,2,5,6-dibenzocyclooctadiene are obtained by the reaction of α,α'-dibromo-o-xylene with (Ph3P)2Ni(C2H4).In ether oxidative addition of 1,2-dibromoethane is not observed.
