76185-75-6Relevant academic research and scientific papers
REGIOSELECTIVITY OF THE ADDITION OF THIOLS TO 1-R-3-METHYLBICYCLOBUTANES
Vasin, V. A.,Razin, V. V.,Bolusheva, I. Yu.,Tanaseichuk, B. S.,Surmina, L. S.,Zefirov, N. S.
, p. 469 - 477 (2007/10/02)
The radical addition of thiols to 1-cyano-, 1-methoxycarbonyl-, 1-tert-butoxycarbonyl-, 1-acetyl-, and 1-benzoyl-3-methylbicyclobutanes was studied by GLC and PMR.In the case of thiophenol it was shown that the regioselectivity and relative reactivity of addition are determined by the polarity of the substituent.This is reflected in the satisfactory correlation between these values and the Taft ? constants.
ADDITION TO BICYCLOBUTANE DERIVATIVES. V. ADDITION OF SODIUM METHANETHIOLATE AND THIOPHENOLATE TO 1-BICYCLOBUTANECARBONITRILE AND 3-METHYL- AND 3-PHENYL-1-BICYCLOBUTANECARBONITRILES
Razin, V. V.,Vasin, V. A.,Ogloblin, K. A.
, p. 836 - 840 (2007/10/02)
Sodium methanethiolate and thiophenolate add to unsubstituted 1-bicyclobutanecarbonitrile and also to its 3-methyl and 3-phenyl derivatives in a methanol medium exclusively at the central bicyclobutane C-C bond with nucleophilic attack at the β position t
