76189-76-9Relevant articles and documents
Palladacycle-catalyzed asymmetric intermolecular construction of chiral tertiary P-heterocycles by stepwise addition of H-P-H bonds to bis(enones)
Huang, Yinhua,Pullarkat, Sumod A.,Teong, Siewping,Chew, Renta Jonathan,Li, Yongxin,Leung, Pak-Hing
experimental part, p. 4871 - 4875 (2012/10/08)
A palladacycle-catalyzed diastereo- and enantioselective stepwise double hydrophosphination of bis(enones) with PhPH2 has been developed, allowing intermolecular construction of chiral tertiary bulky P-heterocycles in one pot in high yields. A catalytic cycle for the reaction is proposed as well.