76189-77-0Relevant academic research and scientific papers
Palladacycle-catalyzed asymmetric intermolecular construction of chiral tertiary P-heterocycles by stepwise addition of H-P-H bonds to bis(enones)
Huang, Yinhua,Pullarkat, Sumod A.,Teong, Siewping,Chew, Renta Jonathan,Li, Yongxin,Leung, Pak-Hing
experimental part, p. 4871 - 4875 (2012/10/08)
A palladacycle-catalyzed diastereo- and enantioselective stepwise double hydrophosphination of bis(enones) with PhPH2 has been developed, allowing intermolecular construction of chiral tertiary bulky P-heterocycles in one pot in high yields. A catalytic cycle for the reaction is proposed as well.
Bulky 4-phosphacyclohexanones: Diastereoselective complexations, orthometallations and unprecedented [3.1.1]metallabicycles
Doherty, Ruth,Haddow, Mairi F.,Harrison, Zoe A.,Orpen, A. Guy,Pringle, Paul G.,Turner, Alex,Wingad, Richard L.
, p. 4310 - 4320 (2007/10/03)
The 4-phosphacyclohexanones, 2,2,6, 6-tetramethyl-1-phenyl-4-phosphorinanone (La), 1,2,6-triphenyl-4-phosphorinanone (PhLb), 1-cyclohexyl-2,6-diphenyl-4-phosphorinanone (CyLb) and 1-tert-butyl-2,6-dip
A Novel Isomerization of Certain Substituted 1,2,6-Triphenyl-4-phosphorinanones. Stereochemical and Conformational Analysis of Substituted 1,2,6-Triphenyl-4-phosphorinanones and 2,6-Diphenyl-4-thianones via Ultraviolet Spectrometry, 13C NMR Spe
Rampal, Jang B.,Satyamurthy, Nagichettiar,Bowen, John M.,Purdie, Neil,Berlin, K. Darrell
, p. 7602 - 7609 (2007/10/02)
A series of 1,2,6-triphenyl-substituted phosphorinan-4-ones with methyl substituents at C(3) or with two methyl substituents at C(3,5) have been prepared via a condensation of the appropriate 1,5-diphenylpentadien-3-one and bis(hydroxymethyl)phenylphosphi
