76200-31-2Relevant academic research and scientific papers
Reactions of the Carbanion from an Orsellinate Derivative with Electrophiles
Carpenter, T. Adrian,Evans, Geoffrey E.,Leeper, Finian J.,Staunton, James,Wilkinson, Michael R.
, p. 1043 - 1051 (2007/10/02)
Esters of orsellinic acid dimethyl ether (11) are attacked by alkyl-lithium reagents to give ketones and in some cases smaller amounts of alkenes as a result of a second nucleophilic attack.However at -78 deg C attack on (11) by its own anion (10) is suff
ON THE REACTION OF ORSELLINIC ACID CARBANION WITH PYRYLIUM SALTS
Hoefle, Gerhard,Schneider, Guenther,Roeser, Karl
, p. 1633 - 1636 (2007/10/02)
From the reaction of methyldimethyl orsellinate anion 1 with the pyrylium salt 2 the isocumarin 5 was isolated in addition to the pyrones 3 and 4.Reaction intermediates could be trapped as pyridines 6 and 7.
