762273-27-8Relevant academic research and scientific papers
Intermolecular enolate heterocoupling: Scope, mechanism, and application
DeMartino, Michael P.,Chen, Ke,Baran, Phil S.
supporting information; experimental part, p. 11546 - 11560 (2009/02/03)
This full account presents the background on, discovery of, and extensive insight that has been gained into the oxidative intermolecular coupling of two different carbonyl species. Optimization of this process has culminated in reliable and scalable proto
Access to functionalized cyclopropylcarbinyl compounds from homoallylic ethers via zirconocene intermediates
Vasse, Jean-Luc,Szymoniak, Jan
, p. 6449 - 6451 (2007/10/03)
Cyclopropylcarbinylzirconium complexes were generated from homoallylic ethers and zirconocene (Cp2ZrCl2/2n-BuLi). They underwent further in situ transformations that is, bromination-substitution, transmetallation-functionalization and insertion reactions to afford various cyclopropylcarbinyl derivatives. In contrast, ring-opening products could be selectively obtained by treating the zirconium complex with MeLi, prior to functionalization.
